منابع مشابه
Dynamic Nuclear Polarization of Oxygen-17.
Oxygen-17 detected DNP NMR of a water/glycerol glass enabled an 80-fold enhancement of signal intensities at 82 K, using the biradical TOTAPOL. The >6,000-fold savings in acquisition time enables (17)O-(1)H distance measurements and heteronuclear correlation experiments. These experiments are the initial demonstration of the feasibility of DNP NMR on quadrupolar (17)O.
متن کاملDynamic Nuclear Polarization of [superscript 17] O: Direct Polarization
Dynamic nuclear polarization of 17O was studied using four different polarizing agents – the biradical TOTAPOL, and the monoradicals trityl and SA-BDPA, as well as a mixture of the latter two. Field profiles, DNP mechanisms and enhancements were measured to better understand and optimize directly polarizing this low-gamma quadrupolar nucleus using both monoand bi-radical polarizing agents. Enha...
متن کاملCross-polarization for dissolution dynamic nuclear polarization.
Dynamic nuclear polarization (DNP) in combination with subsequent dissolution of the sample allows the detection of low-γ nuclei in the solution state with a signal gain of up to tens of thousand times compared to experiments starting from Boltzmann conditions. The long polarization build-up times of typically more than one hour are a drawback of this technique. The combination of dissolution D...
متن کاملChemically Induced Dynamic Nuclear Polarization
N M R emission and e n h a n c e d absorpt i on o f p roduc t s o f radical react ions ( C I D N P ) is e x p l a i n e d b y nuc lear spin d e p e n d e n t ad iabat i c transit ions be tween singlet a n d tr iplet states o f transient radical pairs. I n m a g n e t i c fields larger than a b o u t 1 k G o n l y S — To-transit ions c ont r ibute t o nuc lear polar izat ion. F r o m a k inet i ...
متن کاملHigh frequency dynamic nuclear polarization.
During the three decades 1980-2010, magic angle spinning (MAS) NMR developed into the method of choice to examine many chemical, physical, and biological problems. In particular, a variety of dipolar recoupling methods to measure distances and torsion angles can now constrain molecular structures to high resolution. However, applications are often limited by the low sensitivity of the experimen...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry Letters
سال: 2012
ISSN: 1948-7185
DOI: 10.1021/jz300742w